In 1911 Rutherford conducted an experiment which grounded the modern view of the structure of the atom. He discovered that an atom is mostly empty space with a small positive nucleus. The nucleus is composed of two nucleons, protons with charge +e and uncharged neutrons.
Rutherford's experiment
Rutherford's experiment was conducted in 1911 and consisted in firing alpha particles to a thin metal foil. He found that most of the particles passed straight through while only some were deflected and a few of them were even sent back.
The apparatus
The experiment consisted in a beam of alpha particles being targeted towards a piece of gold foil in a vacuum. The alpha particles were scattered by the foil, which was only a few atomic layers thick, and detected by a fluorescent zinc sulfide screen. This screen was mounted on a microscope that could move around the set up by about 180° and would produce a speck of light for every particle hitting it.
1.
Alpha particle source
2.
Alpha particle beam
3.
Gold foil
4.
Fluorescent screen
5.
Microscope
6.
Observer
7.
Evacuated container
Thus, Rutherford was able to count the number of scattered alpha particles for an angle θ per minute.
Observations and conclusions
Rutherford made two significant observations that led him to make two conclusions about the structure of the atom:
observation
conclusion
Most of the particles went straight through. Only about 1 in 2000 were scattered.
The atom is mostly empty with most of its mass concentrated in a nucleus.
About 1 in 10000 particles were deflected by more than 90°.
The nucleus has a positive charge.
1.
Alpha particle source
2.
Gold nuclei scattering the particles
Since alpha particles are positive the nucleus must also be positive for the particles to be deflected by such high angles, which also means that this experiment can be modelled using Coulomb's law. By doing this Rutherford found that the nucleus was roughly 10−14m in size, a good estimate given the true value of around 10−15m.
At the time, the leading theory for the atomic structure was Thomson's plum pudding model, in which the atom was composed of a solid positively charged sphere with negative electrons embedded into it. This experiment disproved it and provided support for the new nuclear model, where the atom consists of a nucleus roughly 10−15m in size and electrons orbit around it.
The nucleus
The nucleus of an atom consists of protons with charge +e, where e=1.6×10−19C, and neutrons with charge 0; these are also known as nucleons.
In an atom electrons with charge −e orbit around it and the overall charge is neutral when the number of protons and electrons is the same.
The nucleus of an atom can be represented as:
ZAX
symbol
definition
X
Chemical symbol of the element.
A
Nucleon number- the total number of protons and neutrons.
Z
Proton/Atomic number- number of protons.
N
Neutron number- number of neutrons, can be found with N=A−Z.
Atoms that are the same element (sameZ) but have differing numbers of neutrons (differentN) are called isotopes.
Example
Given the neutral isotope uranium-235, write down the number of neutrons and electrons in it.
First, by looking at a periodic table write down all the values:
A=235Z=92
Next, write down the equation you need:
N=A−Z
Substitute values into the equation:
N=235−92
Work out the answer:
N=143
Now remember that for a neutral atom the number of electrons is equal to Z, hence:
The number of neutrons and electrons in a neutral uranium-235 atom is 143 and 92 respectively.
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FAQs - Frequently Asked Questions
What were the observations of Rutherford's experiment?
Rutherford's experiment found that most of the particles passed straight through the gold foil while only some were deflected and a few of them were even sent back.
What is the nuclear model?
The nuclear model of the atom consists of a positive nucleus roughly x10^−15 m in size and electrons orbit around it.
What did Rutherford's experiment discover?
Rutherford's experiment discovered that an atom consists of mostly empty space with a small positive nucleus at its center.