Isotopes and radioactive decay
In a nutshell
An isotope is an atom of the same element that has a different amount of neutrons. Some isotopes are unstable and will radioactively decay into other elements. The radioactive decay types are alpha, beta and gamma. The mass and atomic numbers change during alpha and beta decay.
Key properties of decay
Type | symbol | Form | Ionising power | Range in air | Absorbed by... |
Alpha | | Helium nucleus | Heavily ionising | | Paper |
Beta | | High-speed electron | Moderately ionising | A few metres | Aluminium |
Gamma | | High-frequency EM wave | Weakly ionising | A few kilometres | Lead |
Isotopes
Whilst the nucleus of an atom of a certain element always has a specific number of protons, atoms of the same element may differ in nuclear mass. As nuclear mass concerns neutrons and protons and the number of protons does not change, it means that the neutron number changes for an atom of different nuclear mass.
An isotope is an atom of the same element that has a different amount of neutrons. A neutron has no charge so this doesn't affect the charge of an atom.
Example
Helium, 24He, has two protons and two neutrons. The helium isotope 23He has two protons and one neutron.
Isotopes occur naturally, but some are rarer than others.
Example
Only about two in every 10,000 hydrogen atoms is the deuterium isotope 12H. Only about one in every 1018 hydrogen atoms is the tritium isotope 13H.
Isotopes are not always stable, generally only one or two isotopes of an element will be stable. An unstable isotope will decay into another element and give out radiation. They do this in an attempt to become more stable. This process is called radioactive decay.
Curiosity: Isotopes of large atoms (like uranium) tend to be unstable due to their large size and the imbalance of protons and neutrons in the nucleus.
Ionising radiation is radiation that gives electrons enough energy to leave the atom. This results in positive ions. A radiation source's ionising power is how easily it can do this.
Radioactive decay
There are three types of radioactive decay to learn: alpha, beta and gamma. These are named after the particle they emit in the process.
| 1. | Alpha particle | 2. | Gamma particle | 3. | Beta particle | |
Type of decay | Explanation |
Alpha | Alpha decay causes an alpha (α) particle to be emitted from the nucleus.
An α-particle is identical to a helium nucleus (24He) and is made up of two neutrons and two protons. They don't penetrate very far into materials and are absorbed by paper. Their large size makes them highly ionising. |
Beta | Beta decay emits a fast-moving electron and changes a neutron to a proton in the nucleus.
A beta particle (β-particle) has nearly zero mass and a relative charge of −1. They penetrate moderately far into materials and are absorbed by aluminium. They are moderately ionising. |
Gamma | Gamma decay emits radiation in the form of high-frequency electromagnetic waves (γ). They penetrate very far into materials and are only absorbed by thick sheets of lead or metres of concrete. They are weakly ionising.
|
Penetrating power
| 1. | Alpha particle | 2. | Beta particle | 3. | Gamma ray | 4. | Paper | 5. | A few cm of aluminium | 6. | | |
Nuclear equations
Radioactive decays can be represented by nuclear equations using element symbols. Element symbols show the atomic (proton) number, the mass (sum of nucleons) number and the corresponding element.
Example
An alpha particle is written as 24He. A beta particle is written as −10e. A gamma particle is written as γ (it does not have a mass or atomic number).
The total mass number and the total atomic number must be equal on both sides of a nuclear equation.
Alpha decay
The nuclear equation for alpha decay is
BAX→B−2A−4Y+24He
Example
Uranium-238 decays into thorium-234 by alpha decay.
92238U→90234Th+24He
Tip: Notice how the quantities along the top (mass number) add up to 238 on both sides of the arrow. And the quantities along the bottom (atomic number) add up to 92 on both sides of the arrow. This follows the rule for writing nuclear equations.
Beta decay
The nuclear equation for beta decay is
BAX→B+1AY+−10e
Example
Lithium can undergo beta decay.
38Li→48Be+−10e
Gamma decay
Gamma rays only carry energy so do not change the mass or atomic number of an atom. The nuclear equation for gamma decay is
BAX→BAX+γ
Example
Barium-137 can decay by gamma decay.
56137Ba→56137Ba+γ