Hydrolysis is the breaking of a molecule using water. Polymers can be hydrolysed in the presence of a catalyst to increase the rate of reaction. Hydrolysis using water only is a slow process.
The products of hydrolysis are the monomers (or monomer derivatives) of the polymer. Either two products will form or in the case of a complex polymer one product will be produced which contains two different functional groups.
Acid hydrolysis
Polymers can be split in the presence of water and an acid catalyst, such as dilute sulfuric acid.
If there is an excess amount of hydrogen ions, hydrolysis of polyamide will lead to the formation of an ammonium ion/salt due to the protonation of the nitrogen.
General
Example
Base hydrolysis
Polymers can be split in the presence of water and a base catalyst, such as sodium hydroxide.