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Chemical and fuel cells

Chemical and fuel cells

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Summary

​Chemical and fuel cells

In a nutshell

Cells contain chemicals which react to produce electricity. The voltage produced by a cell is dependent upon a number of factors including the type of electrode and electrolyte.


Equations


word equation

symbol equation

​hydrogen→two hydrogen ions+two electronshydrogen \rightarrow two~hydrogen~ions+two~electrons​​
​H2→2H++2e– H_2 → 2H^+ + 2e^–​​
​four hydrogen ions+oxygen+four electrons→two water moleculesfour ~hydrogen~ions +oxygen+four~electrons\rightarrow two~water~molecules​​
​4H++O2+4e–→2H2O4H^+ + O_2 + 4e^– → 2H_2O​​
​hydrogen+oxygen→waterhydrogen+oxygen\rightarrow water​​
​2H2+O2→2H2O2H_2 + O_2→ 2H_2O​​

​​​

Definitions


Electrode
An electrical metal conductor which is in contact with the electrolyte.

Electrolyte
An ionic compound which is dissolved in aqueous solution (water) or molten (melted) allowing the ions to move freely.

Cell
A cell is a system which produces electricity from chemical reactions.

Battery

A battery is two or more cells connected up together.

Redox
Reduction and oxidation.

Oxidation
Loss of electrons and gain of oxygen.

Reduction
Gain of electrons and loss of oxygen.

Anode
In fuel cells, the anode is the negative electrode. In electrolysis, the anode is the positive electrode.

Cathode
In fuel cells, the cathode is the positive electrode. In electrolysis, the cathode is the negative electrode.



Simple cells

A simple cell produces a voltage and is made up of two different electrodes dipped in an electrolyte. 

  • The two electrodes are made up of different metals.
  • The greater the difference in reactivity between the two metals, the greater the voltage.
  • Different electrolytes react with electrodes differently, which affects the magnitude of voltage.


A simple cell consists of a voltmeter connected to a negative electrode and positive electrode to measure the voltage. The two electrodes are immersed in an electrolyte.


Chemistry; Separate chemistry 1; KS4 Year 10; Chemical and fuel cells
1.
Voltmeter
2.
Negative electrode
3.
Positive electrode
4.
Electrolyte



Non-rechargeable vs chargeable batteries

In non-rechargeable batteries:

  • The reaction is irreversible
  • Reactants in the electrolyte and electrode get used up after a period of time
  • The battery cannot be re-charged

Example

Alkaline batteries


In rechargeable batteries, the battery can be recharged by applying an external electrical current to reverse the reaction.


Example

Phone batteries



Hydrogen fuel cells

Definition

Hydrogen fuel cells are electrochemical cells which produce electricity and are used as an alternative to petrol and diesel. 

Hydrogen gas from the fuel reacts with oxygen in the air:
1.
Electrical circuit
2.
Anode
3.
Acidic electrolyte
4.
Cathode
A.
Hydrogen fuel fed in at the anode.
B.
Oxygen fed in at the cathode. 
C.
Water that is produced can exit at the anode.
D.
Unreacted oxygen exits at the cathode. 


PROCEDURE 

1.
An acid is used as the electrolyte.
2.
Hydrogen fuel is oxidised at the anode to produce hydrogen ions:
 hydrogen→two hydrogen ions++two electronsH2→2H++2e–hydrogen \rightarrow two~hydrogen~ions^++two~electrons\newline H_2 → 2H^+ + 2e^–​​
3.
The hydrogen ions migrate to the cathode, where they react with oxygen (from the air) in a reduction reaction:
 four hydrogen ions++oxygen+four electrons→two water molecules4H++O2+4e–→2H2Ofour ~hydrogen~ions^+ +oxygen+four~electrons\rightarrow two~water~molecules\newline4H^+ + O_2 + 4e^– → 2H_2O​​
4.
The movement of electrons from the anode to cathode produces an electrical current.
5.
The overall reaction is:
 hydrogen+oxygen→water2H2+O2→2H2Ohydrogen+oxygen\rightarrow water\newline2H_2 + O_2→ 2H_2O​​


​


Advantages and disadvantages of hydrogen fuel cells 


Advantages

Disadvantages

  • Do not produce atmospheric pollutants
  • More energy efficient than petrol and diesel, as more energy is released per kilogram of fuel
  • Reduces the use and disposal of batteries
  • Exists in the gaseous state so it is difficult and expensive to store; it must be stored under high pressure which is dangerous
  • Hydrogen gas is highly explosive and flammable
  • The production of hydrogen gas usually involves energy-intense processes, such as electrolysis, which uses energy from fossil fuels


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Learn with Basics

Length:
Ions and their formation

Unit 1

Ions and their formation

Electrolysis

Unit 2

Electrolysis

Jump Ahead

Chemical and fuel cells

Unit 3

Chemical and fuel cells

Final Test

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FAQs - Frequently Asked Questions

What is a battery?

What is a cell?

What is an electrolyte?

What is an electrode?

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