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Group 1: properties and reactivity

Group 1: properties and reactivity

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Summary

Group 1: properties and reactivity

In a nutshell

Group 11​ metals have a range of properties. They react with non-metals by forming ionic bonds.



Alkali metals

The elements of Group 11​ are called alkali metals because they form alkaline solutions when dissolved in water. Like all metals, they are malleable and can conduct electricity. Group 11​ metal ions can be identified by flame tests.


Flame tests are carried out by dipping a clean, nichrome wire into the metal sample and then passing it through a Bunsen burner with a blue flame.


Group 11​ metal ION

Flame colour

Lithium
Red
Sodium
Yellow
Potassium
Lilac


Chemistry; Groups in the periodic table; KS4 Year 10; Group 1: properties and reactivity



Atomic structure and ionic bonding

Atomic structure

The octet rule specifies that atoms are stable when they have a 'full' outer shell. A full outer shell is equal to eight electrons. Group numbers (columns) in the periodic table tell you how many electrons are in the outer shell of an atom. 


A Group 11​ metal atom has one electron in its outer shell and are therefore unstable due to an incomplete outer shell.


Ionic bonding

An ionic bond is formed from electrostatic forces of attraction between oppositely charged ions.  Group 11​ metals become stable by reacting with non-metal elements to form ionic compounds. In doing so, a full outer shell is formed. Group 11​ metals lose one electron to form 1+1+​ ions. This electron is donated to a non-metal which forms a negative ion. This results in the formation of an ionic bond. 



Lithium bromide (LiBrLiBr) forms by ionic bonding. The lithium atom donates an electron to bromine, it then becomes a positively charged ion and bromine becomes a negatively charged bromide ion. Electrostatic forces between these oppositely charged ions allows the ionic compound lithium bromide to form. 


Trends in reactivity 

Reactivity increases down Group 11​, as the atom size increases down the group. There are therefore more electron shells, so the outer electron is further away from the nucleus as you go down the group. The outer electron is easier to 'lose' because it is less attracted to the nucleus, this increases reactivity down the group.



Reactions  



Oxygen

Water

Chlorine

Lithium

lithium+oxygenlithium oxidelithium + oxygen \rightarrow lithium~ oxide​​

4Li+O22Li2O4Li + O_2 \rightarrow 2Li_2O​​
lithium+waterlithium hydroxide+hydrogenlithium + water \rightarrow lithium~ hydroxide + hydrogen​​

2Li+2H2O2LiOH+H22Li + 2H_2O \rightarrow2LiOH + H_2​​
lithium+chlorinelithium chloridelithium + chlorine \rightarrow​ lithium~ chloride​​

2Li+Cl22LiCl2Li + Cl_2 \rightarrow 2LiCl​​

Sodium

sodium+oxygensodium oxidesodium + oxygen ​ \rightarrow sodium ~oxide ​​

4Na+O22Na2O4Na + O_2 \rightarrow 2Na_2O​​
sodium+watersodium hydroxide+hydrogensodium + water \rightarrow sodium~ hydroxide + hydrogen​​

2Na+2H2O2NaOH+H22 Na + 2H_2O \rightarrow 2NaOH + H_2​​
sodium+chlorinesodium chloridesodium + chlorine \rightarrow sodium ~chloride​​

2Na+Cl22NaCl2Na + Cl_2 \rightarrow2NaCl​​

Potassium

potassium+oxygenpotassium oxidepotassium + oxygen \rightarrow potassium~ oxide​​

4K+O22K2O4K + O_2 \rightarrow 2K_2O​​
potassium+waterpotassium hydroxide+hydrogenpotassium + water \rightarrow potassium ~hydroxide + hydrogen​​

2K+2H2O2KOH+H22K + 2H_2O \rightarrow2KOH + H_2​​
potassium+chlorinepotassium chloridepotassium + chlorine\rightarrow potassium~ chloride​​

2K+Cl22KCl2K + Cl_2 \rightarrow 2KCl​​


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Learn with Basics

Length:
Everyday materials and their properties

Unit 1

Everyday materials and their properties

The properties of metals

Unit 2

The properties of metals

Jump Ahead

Group 1: properties and reactivity

Unit 3

Group 1: properties and reactivity

Final Test

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FAQs - Frequently Asked Questions

Are group 1 metals stable?

What is an ionic bond?

How does reactivity change as you go down group 1?

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